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Fuel cell vehicles are the subject of extensive research and development because of their potential for high efficiency and low emissions. Because fuel cell vehicles remain expensive and the demand for hydrogen is therefore limited, very few fueling stations are being built. To try to accelerate the development of a hydrogen economy, some original equipment manufacturers (OEM) in the automotive industry have been working on a hydrogen-fueled internal combustion engine (ICE) as an intermediate step. Despite its lower cost, the hydrogen-fueled ICE offers, for a similar amount of onboard hydrogen, a lower driving range because of its lower efficiency. This paper compares the fuel economy potential of hydrogen-fueled vehicles to their conventional gasoline counterparts. To take uncertainties into account, the current and future status of both technologies were considered.

The non-uniform character of the torque produced by a reciprocating I.C. engine is reflected in the cyclic variation of the crankshaft's speed. Because the crankshaft is an elastic structure, its response to the different harmonic components of the torque is different and changes with engine speed. The lowest harmonic components of the engine torque do not excite torsional vibrations and correlate fairly well with the corresponding harmonic orders of the crankshaft's speed. Based on a random vector model of the harmonic components of the gas-pressure torque, a statistical correlation is obtained between amplitudes and phases of the same harmonic component of the gas-pressure torque and of the crankshaft's speed. The lowest major harmonic order determines the average IMEP of the engine and the half-order detects if a cylinder is a lesser contributor to the total engine output and identifies the deficient cylinder.

When comparing the potential of advanced versus conventional powertrains, a traditional approach is to hold glider design constant and simulate “comparable performance” to a conventional vehicle (CV). However, manufacturers have developed hybrid electric vehicle (HEV), plug-in hybrid electric vehicle (PHEV), and all-electric vehicle (EV) powertrains in gliders designed to synergistically enhance fuel saving benefits of such powertrains by further reducing road load and engine output power (or continuous power for the EV) where no conventional powertrain option is provided. In the U.S. marketplace, there are now several examples of both hybrid and plug-in hybrid electric vehicles using gliders common to top selling CVs and a few using low load gliders to further reduce fuel consumption.

Onboard reforming of petroleum-based fuels, such as gasoline, may help ease the introduction of fuel cell vehicles to the marketplace. Although gasoline can be reformed, it is optimized to meet the demands of ICEs. This optimization includes blending to increase the octane number and addition of oxygenates and detergents to control emissions. The requirements for a fuel for onboard reforming to hydrogen are quite different than those for combustion. Factors such as octane number and flame speed are not important; however, factors such as hydrogen density, catalyst-fuel interactions, and possible catalyst poisoning become paramount. In order to identify what factors are important in a hydrocarbon fuel for reforming to hydrogen and what factors are detrimental, we have begun a program to test various components of gasoline and blends of components under autothermal reforming conditions. The results indicate that fuel composition can have a large effect on reforming behavior.

In this study, residual gas fraction measurements in a spark-ignition engine were carried out using an optical sensor installed in the spark plug with infrared absorption method. The residual gas fraction inside engine cylinder is proportional to the CO2 concentration. Infrared absorption method was applied and an infrared lamp and optical filter (center wavelength: around 4.3 μm) that coincides with the absorption lines of CO2 was used as a light source.The molar absorption coefficient of CO2 is discussed and compared to results in the HITRAN database. The effect of water vapor absorption doesn't affect the absorption of CO2. The absorption characteristics of CO2 were determined in advance using a constant volume vessel. Molar absorption coefficient depends on the CO2 concentration and ambient pressure and temperature, and wavelength of absorption line.

With increasing interest to reduce the dependency on gasoline and diesel, alternative energy source like compressed natural gas (CNG) is a viable option for internal combustion engines. Spark-ignited (SI) CNG engine is the simplest way to utilize CNG in engines, but direct injection (DI) Diesel-CNG dual-fuel engine is known to offer improvement in combustion efficiency and reduction in exhaust gases. Dual-fuel engine has characteristics similar to both SI engine and diesel engine which makes the combustion process more complex. This paper reports the computational fluid dynamics simulation of both DI dual-fuel compression ignition (CI) and SI CNG engines. In diesel-CNG dual-fuel engine simulations and comparison to experiments, attention was on ignition delay, transition from auto-ignition to flame propagation and heat released from the combustion of diesel and gaseous fuel, as well as relevant pollutants emissions.

Late-injection low-temperature diesel combustion is found to further reduce NOx and soot simultaneously. The combustion phenomena and detail chemical kinetics are studied with high speed spray/combustion images and time-resolved spectroscopy analysis in a rapid compression machine (RCM) with a small bowl combustion chamber. High swirl and high EGR condition can be achieved in the RCM; variable injection pressure and injection timing is supplied by the high-pressure common-rail fuel injection system. Effect of small amount of premix hydrogen gas on diesel combustion is also studied in the RCM. A hydrogen injector is located in the upstream of air inlet for delivery small amount and premixed hydrogen gas into cylinder just before the compression stroke. The ignition delay is studied both from the pressure curves and the chemiluminescence images.

Currently there is a significant research effort being made in gasoline spark/ignition (SI) engines to understand and reduce cycle-to-cycle variations. One of the phenomena that presents this cycle-to-cycle variation is combustion knock, which also happens to have a very stochastic behavior in modern SI engines. Conversely, the CFR octane rating engine presents much more repeatable combustion knock activity. The aim of this study is to assess the impact of fuel composition on the cycle to cycle variation of the pressure and timing of end gas autoignition. The variation of cylinder conditions at the timing of end-gas autoignition (knock point) for a wide selection of cycle ensembles have been analyzed for several constant RON 98 fuels on the CFR engine, as well as in a modern single-cylinder gasoline direct injection (GDI) SI engine operated at RON-like intake conditions.

Alternative fuels for internal combustion engines have been the subject of numerous studies. The new U.S. Renewable Fuel Standard has made it a requirement to increase the production of ethanol and advanced biofuels to 36 billion gallons by 2022. Because corn-based ethanol will be capped at 15 billion gallons, 21 billion gallons must come from the advanced biofuels category. A potential source to fill the gap may be butanol and its isomers as they possess fuel properties superior to ethanol. Recently, concerns have been raised about emission of currently non-regulated constituents, aldehydes in particular, from alcohol-based fuels. In an effort to assess the relative impact of the U.S. Renewable Fuel Standards on emissions from a modern gasoline engine, both regulated and non-regulated gas constituents were measured from the combustion of three different alcohol isomers in a modern direct-injected (DI) spark ignition (SI) gasoline engine.

Misfiring or partial combustion during diesel engine operation results in the production of partial oxidation products such as ethylene (C₂H₄), carbon monoxide and aldehydes, in particular formaldehyde (HCHO). These compounds remain in the cylinder as residual gases to participate in the following engine cycle. Carbon monoxide and formaldehyde have been shown to exhibit a dual nature, retarding ignition in one temperature regime, yet decreasing ignition delay periods of hydrocarbon mixtures as temperatures exceed 1000°K. Largely unknown is the synergistic effects of such species. In this work, varying amounts of C₂H₄ and HCHO are added to the intake air of a naturally aspirated optical diesel engine and their combined effect on autoignition and subsequent combustion is examined. To observe the effect of these dopants on the low-temperature heat release (LTHR), ultraviolet chemiluminescent images are recorded using intensified CCD cameras.

Hydrogen is considered one of the most promising future energy carriers and transportation fuels. Because of the lack of a hydrogen infrastructure and refueling stations, widespread introduction of vehicles powered by pure hydrogen is not likely in the near future. Blending hydrogen with methane could be one solution. Such blends take advantage of the unique combustion properties of hydrogen and, at the same time, reduce the demand for pure hydrogen. In this paper, the authors analyze the combustion properties of hydrogen/methane blends (5% and 20% methane [by volume] in hydrogen equal to 30% and 65% methane [by mass] in hydrogen) and compare them to those of pure hydrogen as a reference. The study confirms that only minor adjustments in spark timing and injection duration are necessary for an engine calibrated and tuned for operation on pure hydrogen to run on hydrogen/methane blends.

Ethanol has received both positive and negative attention as a renewable fuel for spark ignition engines. Studies of ethanol have shown improved volumetric efficiency, knock tolerance, and favorable burn curves[1]. Nevertheless, little research has been published exploring the impact of ethanol blends on race engine performance coupled with the impact on well-to-wheels (WTW) greenhouse gases, emissions, and petroleum reduction. In this work, a circle track race vehicle powered by a GM Performance Parts 6.2L OHV CT-525 engine was tested using 100 octane race fuel and E85 over a matrix of configurations. Carburetion vs. fuel injection configurations were benchmarked with both fuels, with the addition of 100- and 300-cells-per-inch catalytic convertors. Testing involved both dynamometer testing and on-track testing utilizing a portable emissions measurement system.

Recent advances in fuel-cell technology and low-emission, direct-injection spark-ignition and diesel engines for vehicles could significantly change the transportation vehicle power plant landscape in the next decade or so. This paper is a scoping study that compares total fuel cycle options for providing power to personal transport vehicles. The key question asked is, “How much of the energy from the fuel feedstock is available for motive power?” Emissions of selected criteria pollutants and greenhouse gases are qualitatively discussed. This analysis illustrates the differences among options; it is not intended to be exhaustive. Cases considered are hydrogen fuel from methane and from iso-octane in generic proton-exchange membrane (PEM) fuel-cell vehicles, methane and iso-octane in spark-ignition (SI) engine vehicles, and diesel fuel (from methane or petroleum) in direct-injection (DI) diesel engine vehicles.

An increase in spark-ignition engine efficiency can be gained by increasing the engine compression ratio, which requires fuels with higher knock resistance. Oxygenated fuel components, such as methanol, ethanol, isopropanol, or iso-butanol, all have a Research Octane Number (RON) higher than 100. The octane numbers (ON) of fuels are rated on the CFR F1/F2 engine by comparing the knock intensity of a sample fuel relative to that of bracketing primary reference fuels (PRF). The PRFs are a binary blend of iso-octane, which is defined to an ON of 100, and n-heptane, which represents an ON of 0. Above 100 ON, the PRF scale continues by adding diluted tetraethyl lead (TEL) to iso-octane. However, TEL is banned from use in commercial gasoline because of its toxicity. The ASTM octane number test methods have a “Fit for Use” test that validate the CFR engine’s compliance with the octane testing method by verifying the defined ON of toluene standardization fuels (TSF).

Hydrogen is considered one of the most promising future energy carriers. There are several challenges that must be overcome in order to establishing a “hydrogen economy”, including the development of a practical, efficient, and cost-effective power conversion device. Using hydrogen as a fuel for internal combustion engines is a huge step toward developing a large-scale hydrogen infrastructure. This paper summarizes the testing of a hydrogen powered pick-up truck on a chassis dynamometer. The vehicle is powered by a port-injected 8-cylinder engine with an integrated supercharger and intercooler. The 4-wheel drive chassis dynamometer is equipped with a hydrogen delivery, metering and safety system as well as hydrogen specific instrumentation. This instrumentation includes numerous sensors, includes a wide-band lambda sensor and an exhaust gas hydrogen analyzer. This analyzer quantifies the amount of unburned hydrogen in the exhaust indicating the completeness of the combustion.

A heterodyne interferometry system with a fiber-optic sensor was developed to measure the temperature history of unburned gas in an engine cylinder. A polarization-preserving fiber and metal mirror were used as the fiber-optic sensor to deliver the test beam to and from the measurement region. This fiber-optic sensor can be assembled in the engine cylinder or the cylinder head without a lot of improvements of an actual engine. The feasibility of our system was sufficient to be applied to temperature history measurement of an unburned gas compressed by flame propagation in an engine cylinder. The resolution of the temperature measurement is approximately 0.7 K, and is dependent on both the sampling clock speed of the A/D converter and the length of the measurement region.

Investigation of knocking combustion in a hydrogen spark-ignition engine is one of the major challenges for future vehicle development. The knock phenomenon in a Spark-Ignition (SI) engine is caused by autoignition of the unburned gas ahead of the flame. The explosive combustion of the end-gas creates a pressure wave that leads to damage of the cylinder wall and the piston head of the engine. We observed autoignition in the end-gas region due to compression by the propagating flame front using a high-speed colour video camera through the optically accessible cylindrical quartz window on the top of the cylinder head. Moreover, a high-speed monochrome video camera operating at a speed of 250, 000 frame/s was used to measure the pressure wave propagation. The goal of this research was to improve our ability to describe the effect of the autoignition process on the end-gas and propagating pressure wave during knocking combustion with the help of a high-speed video camera.

Dimethyl ether (DME) is an alternative to diesel fuel for use in compression-ignition engines with modified fuel systems and offers potential advantages of efficiency improvements and emission reductions. DME can be produced from natural gas (NG) or from renewable feedstocks such as landfill gas (LFG) or renewable natural gas from manure waste streams (MANR) or any other biomass. This study investigates the well-to-wheels (WTW) energy use and emissions of five DME production pathways as compared with those of petroleum gasoline and diesel using the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET®) model developed at Argonne National Laboratory (ANL).

The potential peaking of world conventional oil production and the possible imperative to reduce carbon emissions will put great pressure on vehicle manufacturers to produce more efficient vehicles, on vehicle buyers to seek them out in the marketplace, and on energy suppliers to develop new fuels and delivery systems. Four cases for stabilizing or reducing light vehicle fuel use, oil use, and/or carbon emissions over the next 50 years are presented. Case 1 - Improve mpg so that the fuel use in 2020 is stabilized for the next 30 years. Case 2 - Improve mpg so that by 2030 the fuel use is reduced to the 2000 level and is reduced further in subsequent years. Case 3 - Case 1 plus 50% ethanol use and 50% low-carbon fuel cell vehicles by 2050. Case 4 - Case 2 plus 50% ethanol use and 50% low-carbon fuel cell vehicles by 2050. The mpg targets for new cars and light trucks require that significant advances be made in developing cost-effective and very efficient vehicle technologies.